Skip to main content
Skip to footer
J. Rosenboom, F. Taube, L. Teichmeier, A. Villinger, M. Reinhard, S. Demeshko, M. Bennati, J. Bresien, B. Corzilius, and A. Schulz: Rational Design of a Phosphorus-Centered Disbiradical , Angew. Chem. Int. Ed. 63 , e202318210:1–7 (2024); Design eines Phosphor-zentrierten Disbiradikals , Angew. Chem. 136 , e202318210 (2024). H. Beer, J.-E. Siewert, M. Schröder, M. Fischer, B. Corzilius, and C. Hering-Junghans: Phosphaarsenes – Combining Phospha- and Arsa-Wittig-Reagents , ChemPlusChem 89 , e202400120:1–7 (2024). S. Li, M. Schröder, A. Prudlik, X. Shi, A. Spannenberg, J. Rabeah, R. Francke, B. Corzilius, F. Reiß, and T. Beweries: A General Concept for the Electronic and Steric Modification of 1-Metallacyclobuta-2,3-dienes: A Case Study of Group 4 Metallocene Complexes , Chem. Eur. J. 30 , e202400708:1–11 (2024). J. Huang, M. Klahn, X. Tian, X. Dai, J. Rabeah, V. Aladin, B. Corzilius, S. Bartling, H. Lund, N. Steinfeldt, T. Peppel, A. J. Logsdail, H. Jiao, and J. Strunk: Exfoliated Polymeric Carbon Nitride Nanosheets for Photocatalytic Applications , ACS Appl. Nano Mater. 7 , 7442–7452 (2024). E. Vogelsberg, J. Griebel, I. Engelmann, J. Bauer, F. Taube, B. Corzilius, S. Zahn, A. Kahnt, K. Y. Monakhov, Reversible Optical Switching of Polyoxovanadates and Their Communication via Photoexcited States , Adv. Sci. 11 , 2401595:1–8 (2024). S. Li, M. Schröder, X. Shi, A. Spannenberg, J. Fischer, R. Francke, B. Corzilius, F. Reiß, and T. Beweries, Reactions of Titanium- and Zirconium-Based 1-Metallacyclobuta-2,3-diene Complexes with Diazenes: N═N Bond Cleavage versus N–C Bond Formation and Dearomatization , Organometallics 2024 , in print. Thomas Biedenbänder, Aryana Rodgers, Mirjam Schröder, Liliya Vugmeyster, Björn Corzilius. Investigation of biomolecular dynamics by sensitivity-enhanced 1H–2H CPMAS NMR using matrix-free dynamic nuclear polarization. J. Magn. Reson. Open 21 , 100161 (2024).
N. Alaniva, E. P. Saliba, P. T. Judge, E. L. Sesti, W. Harneit, B. Corzilius, and A. B. Barnes: Electron-decoupled MAS DNP with N@C60 , Phys. Chem. Chem. Phys. 25 , 5343–5347 (2023). V. Aladin, A. K. Sreemantula, T. Biedenbänder, A. Marchanka*, and B. Corzilius*: Specific Signal Enhancement on an RNA-Protein Interface by Dynamic Nuclear Polarization , Chem. Eur. J. 29 , e202203443:1–12 (2023). T. Biedenbänder, E. R. Bensons, and B. Corzilius: Serial Polarization Transfer by Combination of Cross-Relaxation and Rotational Resonance for Sensitivity-Enhanced Solid-State NMR , ChemPhysChem 24 , e202300206 (2023).
R. Nanda, S. Hazan, K. Sauer, V. Aladin, K. Keinan-Adamsky, B. Corzilius, R. Shahar, P. Zaslansky, and G. Goobes: Molecular differences in collagen organization and in organic-inorganic interfacial structure of bones with and without osteocytes , Acta Biomater. 144 , 195–209 (2022). T. Biedenbänder, V. de Jesus, M. Schmidt-Dengler, M. Helm, B. Corzilius, and B. Fürtig: RNA modifications stabilize the tertiary structure of tRNAfMet by locally increasing conformational dynamics , Nucl. Acids Res. 50 , 2334–2349 (2022). T. Biedenbänder, V. Aladin, S. Saeidpour, and B. Corzilius*: Dynamic Nuclear Polarization for Sensitivity Enhancement in Biomolecular Solid-State NMR Chem. Rev. 122 , 9738–9794 (2022). F. He, E. Klein, S. Bartling, S. Saeidpour, B. Corzilius, R. Lesyuk, and C. Klinke: Template-Mediated Formation of Colloidal Two-Dimensional Tin Telluride Nanosheets and the Role of the Ligands , J. Phys. Chem. C 126 , 20498–20504 (2022).
N. Weiß, G. Thielemann, K. Nagel, C. H. Schmidt, A. Seifert, L. Kaßner, V. Strehmel, B. Corzilius, C. Schröder, and S. Spange: The influence of the cation structure on the basicity-related polarity of ionic liquids . Phys. Chem. Chem. Phys. 23 , 26750-26760 (2021).
B. Corzilius*: High-Field Dynamic Nuclear Polarization , Annu. Rev. Phys. Chem. 71 , 143–170 (2020). V. Aladin, P. A. Trenkler, and B. Corzilius*: Heteronuclear Cross-Relaxation under Dynamic Nuclear Polarization in Nicotine and Caffeine , Exp. Results 1 , e10 (2020). V. Aladin and B. Corzilius*: Direct dynamic nuclear polarization as a tool for selective NMR spectroscopy of biomolecules , eMagRes 9 , 239–250 (2020). M. Nguyen, U. Kragl, I. Barke, R. Lange, H. Lund, M. Frank, A. Springer, V. Aladin, B. Corzilius, and D. Hollmann: Coagulation using organic carbonates opens up a sustainable route towards regenerated cellulose film , Commun. Chem. 3 , 116 (2020). J. Heiliger, T. Matzel, E. C. Cetiner, H. Schwalbe*, G. Kuenze*, and B. Corzilius*: Site-specific dynamic nuclear polarization in a Gd(III)-labeled protein , Phys. Chem. Chem. Phys. 22 , 25455–25466 (2020).
V. Aladin, M. Vogel, R. Binder, I. Burghardt, B. Suess, and B. Corzilius*: Complex formation of the tetracycline‐binding aptamer investigated by specific cross‐relaxation under DNP , Angew. Chem. 131 , 4917–4922 (2019); Angew. Chem. Int. Ed. 58 , 4863–4868 (2019). V. Aladin and B. Corzilius*: Methyl dynamics in amino acids modulate heteronuclear cross relaxation in the solid state under MAS DNP , Solid State Nucl. Magn. Reson. 99 , 27–35 (2019). D. Daube, M. Vogel, B. Suess, and B. Corzilius*: Dynamic nuclear polarization on a hybridized hammerhead ribozyme: An explorative study of RNA folding and direct DNP with a paramagnetic metal ion cofactor , Solid State Nucl. Magn. Reson. 101 , 21–30 (2019). J. Mao, V. Aladin, X. Jin, A. J. Leeder, L. J. Brown, R. C. D. Brown, X. He, B. Corzilius, and C. Glaubitz: Exploring Protein Structures by DNP-Enhanced Methyl Solid-State NMR Spectroscopy , J. Am. Chem. Soc. 141 , 19888–19901, (2019).
B. Corzilius*: Dynamic Nuclear Polarization , in: Paramagnetism in Experimental Biomolecular NMR , C. Luchinat, G. Parigi, E. Ravera (Eds.), pp. 219–257, Royal Society of Chemistry, London, 2018 . T. Wittmann, A. Mondal, C. B. L. Tschense, J. J. Wittmann, O. Klimm, R. Siegel, B. Corzilius, B. Weber, M. Kaupp, and J. Senker: Probing Interactions of N-Donor Molecules with Open Metal Sites within Paramagnetic Cr-MIL-101: A Solid-State NMR Spectroscopic and Density Functional Theory Study , J. Am. Chem. Soc. 140 , 2135–2144 (2018). F. J. Scott, E. P. Saliba, B. J. Albert, N. Alaniva, E. L. Sesti, C. Gao, N. C. Golota, E. J. Choi, A. P. Jagtap, J. J. Wittmann, M. Eckardt, W. Harneit, B. Corzilius, S. Th. Sigurdsson, and A. B. Barnes: Frequency-agile gyrotron for electron decoupling and pulsed dynamic nuclear polarization , J. Magn. Reson. 289 , 45–54 (2018). J. J. Wittmann, T. V. Can, M. Eckardt, W. Harneit, R. G. Griffin, and B. Corzilius*: High-precision measurement of the electron spin g factor of trapped atomic nitrogen in the endohedral fullerene N@C60 , J. Magn. Reson. 290 , 12–17 (2018). J.J. Wittmann, M. Eckardt, W. Harneit, and B. Corzilius*: Electron-driven spin diffusion supports crossing the diffusion barrier in MAS DNP , Phys. Chem. Chem. Phys. 20 , 11418–11429 (2018). M.A. Geiger, A.P. Jagtap, M. Kaushik, H. Sun, D. Stöppler, S.T. Sigurdsson*, B. Corzilius*, and H. Oschkinat*: Efficiency of water-soluble nitroxide biradicals for dynamic nuclear polarization in rotating solids at 9.4 T: bcTol-M and cyolyl-TOTAPOL as new polarizing agents , Chem. Eur. J. 24 , 13485-13494 (2018). B. Corzilius*: Paramagnetic metal ions for dynamic nuclear polarization , eMagRes 7 , 179–194 (2018).
M. Kaushik, M. Qi, A. Godt,* and B. Corzilius*: Bis-Gadolinium Complexes for Solid Effect and Cross Effect Dynamic Nuclear Polarization , Angew. Chem. 134 , 4359–4363 (2017); Angew. Chem. Int. Ed. 56 , 4295–4299 (2017). Q. Z. Ni, E. Markhasin, T. V. Can, B. Corzilius, K. O Tan, A. B. Barnes, E. Daviso, Y. Su, J. Herzfeld, and R. G. Griffin: Peptide and Protein Dynamics and Low-Temperature/DNP Magic Angle Spinning NMR , J. Phys. Chem. B 121 , 4997–5006 (2017). A. S. Lilly Thankamony, J. J. Wittmann, M. Kaushik, and B. Corzilius*: Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR , Prog. Nucl. Magn. Reson. Spectrosc. 102–103 , 120–195 (2017).
M. Kaushik, D. Richter, and B. Corzilius*: Dynamic Nuclear Polarization in Solid-state NMR , G.I.T. Laboratory Journal Europe 1-2/2016 , 20. D. Richter, M. Kaushik, and B. Corzilius*: Dynamische Kernpolarisation: Die Empfindlichkeit in der Festkörper-NMR , G.I.T. Labor-Fachzeitschrift 4/2016 , 35. B. Corzilius*: Theory of solid effect and cross effect dynamic nuclear polarization with half-integer high-spin metal polarizing agents in rotating solids , Phys. Chem. Chem. Phys. 18 , 27190–27204 (2016). M. Kaushik, T. Bahrenberg, T. V. Can, M. A. Caporini, R. Silvers, J. Heiliger, A. A. Smith, H. Schwalbe, R. G. Griffin, and B. Corzilius*: Gd(III) and Mn(II) complexes for dynamic nuclear polarization: small molecular chelate polarizing agents and applications with site-directed spin labeling of proteins , Phys. Chem. Chem. Phys. 18 , 27205–27218 (2016). D. Daube, V. Aladin, J. Heiliger, J. J. Wittmann, D. Barthelmes, C. Bengs, H. Schwalbe, and B. Corzilius*: Heteronuclear Cross-relaxation under Solid-state Dynamic Nuclear Polarization , J. Am. Chem. Soc. 138 , 16572–16575 (2016).
P. Wenk, M. Kaushik, D. Richter, M. Vogel, B. Suess, and B. Corzilius*: Dynamic Nuclear Polarization of Nucleic Acid with Endogenously Bound Manganese , J. Biomol. NMR 63 , 97–109 (2015). K. K. Frederick, V. K. Michaelis, B. Corzilius, T.-C. Ong, A. C. Jacavone, R. G. Griffin, and S. Lindquist: Sensitivity Enhanced NMR Reveals Alterations in Protein Structure by Cellular Milieus , Cell 163 , 620–628 (2015).
B. Corzilius, L. B. Andreas, A. A. Smith, Q. Z. Ni, and R. G. Griffin: Paramagnet induced signal quenching in MAS–DNP experiments in frozen homogeneous solutions , J. Magn. Reson. 240 , 113–123 (2014). E. Ravera, B. Corzilius, V. K. Michaelis, C. Luchinat, R. G. Griffin, and I. Bertini: DNP-Enhanced MAS NMR of Bovine Serum Albumin Sediments and Solutions , J. Phys. Chem. B 118 , 2957–2965 (2014). T. V. Can, M. A. Caporini, F. Mentink-Vigier, B. Corzilius, J. J. Walish, M. Rosay, W. E. Maas, M. Baldus, S. Vega, T. M. Swager and R. G. Griffin: Overhauser effects in insulating solids , J. Chem. Phys. 141 , 064202:1–8 (2014). B. Corzilius, V. K. Michaelis, S. A. Penzel, E. Ravera, A. A. Smith, C. Luchinat, and R. G. Griffin: Dynamic Nuclear Polarization of 1 H, 13 C, and 59 Co in a Tris(ethylenediamine)cobalt(III) Crystalline Lattice Doped with Cr(III) , J. Am. Chem. Soc. 136 , 11716–11727 (2014).
E. Ravera, B. Corzilius, V. K. Michaelis, C. Rosa, R. G. Griffin, C. Luchinat, and I. Bertini: Dynamic Nuclear Polarization of Sedimented Solutes , J. Am. Chem. Soc . 135 , 1641–1644 (2013). V. K. Michaelis, A. A. Smith, B. Corzilius, O. Haze, T. M. Swager, and R. G. Griffin: High Field 13 C Dynamic Nuclear Polarization with a Radical Mixture , J. Am. Chem. Soc . 135 , 2935–2938 (2013). T.-C. Ong, M. L. Mak-Jurkauskas, J. J. Walish, V. K. Michaelis, B. Corzilius, A. A. Smith, A. M. Clausen, J. C. Cheetham, T. M. Swager, and R. G. Griffin: Solvent-Free Dynamic Nuclear Polarization of Amorphous and Crystalline Ortho-Terphenyl , J. Phys. Chem. B 117 , 3040–3046 (2013). L. B. Andreas, A. B. Barnes, B. Corzilius, J. J. Chou, E. A. Miller, M. A. Caporini, M. M. Rosay, and R. G. Griffin: Dynamic Nuclear Polarization Study of Inhibitor Binding to the M218-20 Proton Transporter from Influenza A , Biochemistry 52 , 2774-2782 (2013). A. A. Smith, B. Corzilius, and R. G. Griffin: Observation of strongly forbidden solid effect dynamic nuclear polarization transitions via electron-electron double resonance detected NMR , J. Chem. Phys. 139 , 214201:1–6 (2013). V. K. Michealis, B. Corzilius, A. A. Smith, O. Haze, T. M. Swager, and R. G. Griffin: Dynamic Nuclear Polarization of 17 O: Direct Polarization , J. Phys. Chem. B 117 , 14894–14906 (2013). J. Mao, D. Akhmetzyanov, O. Ouari, V. P. Denysenkov, B. Corzilius, J. Plackmeyer, P. Tordo, T. F. Prisner, and C. Glaubitz: Host-Guest Complexes as Water-Soluble High-Performance DNP Polarizing Agents , J. Am. Chem. Soc. 135 , 19275–19281 (2013).
A. A. Smith, B. Corzilius, A. B. Barnes, T. Maly, and R. G. Griffin: Solid Effect Dynamic Nuclear Polarization and Polarization Pathways , J. Chem. Phys. 136 , 015101:1–16 (2012). E. L. Dane, B. Corzilius, E. Rizzato, P. Stocker, T. Maly, A. A. Smith, R. G. Griffin, O. Ouari, P. Tordo, and T. M. Swager: Rigid Orthogonal bis-TEMPO Biradicals with Improved Solubility for Dynamic Nuclear Polarization , J. Org. Chem. 77 , 1789–1797 (2012). M. K. Kiesewetter, B. Corzilius, A. A. Smith, R. G. Griffin, and T. M. Swager: Dynamic Nuclear Polarization with a Water-soluble Rigid Biradical , J. Am. Chem. Soc . 134 , 4538–4540 (2012). B. Corzilius, A. A. Smith, and R. G. Griffin: Solid Effect in Magic Angle Spinning Dynamic Nuclear Polarization , J. Chem. Phys. 137 , 054201:1–12 (2012). A. A. Smith, B. Corzilius, J. A. Bryant, R. DeRocher, P. Woskov, R. J. Temkin, and R. G. Griffin: A 140 GHz Pulsed EPR/212 MHz NMR Spectrometer for DNP Studies , J. Magn. Reson. 223 , 170–179 (2012). O. Haze, B. Corzilius, A. A. Smith, R. G. Griffin, and T. M. Swager: Water-Soluble Narrow-Line Radicals for Dynamic Nuclear Polarization , J. Am. Chem. Soc . 134 , 14287–14290 (2012).
M. Pashchanka, R. C. Hoffmann, O. Burghaus, B. Corzilius, G. Cherkashinin, and J. J. Schneider: Polycrystalline ZnO and Mn-doped ZnO Nanorod Arrays with Variable Dopant Content via a Template Based Synthesis from Zn(II) and Mn(II) Schiff Base Type Single Source Molecular Precursors , Solid State Sci. 13 , 224–231 (2011). E. Nanni, A. B. Barnes, Y. Matsuki, P. P. Woskov, B. Corzilius, R. G. Griffin, and R. J. Temkin: Microwave Field Distribution in a Magic Angle Spinning Dynamic Nuclear Polarization NMR Probe , J. Magn. Reson. 210 , 16–23 (2011).
K.-P. Dinse, J. van Tol, A. Ozarowski, and B. Corzilius: Multi-frequency EPR and DC Conductivity of Itinerant Spins in Single-Wall Carbon Nanotubes , Appl. Magn. Reson. 37 , 595–603 (2010). A. B. Barnes, B. Corzilius, M. L. Mak-Jurkauskas, L. B. Andreas, V. S. Bajaj, Y. Matsuki, M. L. Belenky, J. Lugtenburg, J. R. Sirigiri, R. J. Temkin, J. Herzfeld, and R. G. Griffin: Resolution and Polarization Distribution in Cryogenic DNP/MAS Experiments , Phys. Chem. Chem. Phys. 12 , 5861–5867 (2010). E. Nanni, A. B. Barnes, Y. Matsuki, P. P. Woskov, B. Corzilius, R. G. Griffin, and R. J. Temkin: Optimization of THz Wave Coupling into Samples in DNP/NMR Spectroscopy , 35th International Conference on Infrared, Millimeter and Terahertz Waves (IRMMW-THz) , IEEE, New York, 2010 .
B. Corzilius*, K.-P. Dinse, and K. Hata: Probing the Electronic Properties of Single-Walled Carbon Nanotubes with Resonant and Non-resonant Microwave Absorption , Physica E 40 , 2327–2332 (2008). B. Corzilius*, K.-P. Dinse, K. Hata, M. Haluška, V. Skákalová, and S. Roth: SWNT Probed by Multi-frequency EPR and Nonresonant Microwave Absorption , Phys. Status Solidi B 245 , 2251–2254 (2008).
B. Corzilius, K.-P. Dinse, J. van Slageren, and K. Hata: Low-temperature Anomaly of Microwave Absorption and AC Susceptibility of Single-Wall Carbon Nanotubes: Bulk Superconductivity and Weak Ferromagnetism , Phys. Rev. B 75 , 235416:1–7 (2007). B. Corzilius, K.-P. Dinse, and K. Hata: Single-Wall Carbon Nanotubes and Peapods Investigated by EPR , Phys. Chem. Chem. Phys. 9 , 6063–6072 (2007). B. Corzilius*, S. Agarwal, K.-P. Dinse, and K. Hata: Electron Paramagnetic Resonance and Non-resonant Microwave Absorption of Single Wall Carbon Nanotubes , Phys. Status Solidi B 244 , 3890–3895 (2007). B. Corzilius, P. Jakes, N. Weiden, S. Agarwal, and K.-P. Dinse: EPR Investigation of N@C70 in Polycrystalline C70 and Single Wall Carbon Nanotubes , Mol. Phys. 105 , 2161–2168 (2007).
J. Dannhäuser, W. Donaubauer, F. Hampel, M. Reiher, B. Le Guennic, B. Corzilius, K.-P. Dinse, and A. Hirsch: σ-Donor und π-Acceptor Stacking Interactions in a trans-2-Linked C60 -Cobalt(II) Tetraphenylporphyrin Diad , Angew. Chem. Int. Ed. 45 , 3368–3372 (2006). A. Gembus, B. Corzilius, R.-A. Eichel, K.-P. Dinse, S. Immel, D. Stumm, M. Flauaus, and H. Plenio: Electron Paramagnetic Resonance Structure Investigation of Copper Complexation in a Hemicarcerand , J. Phys. Chem. B 110 , 15012–15020 (2006). B. Corzilius*, A. Gembus, N. Weiden, K.-P. Dinse, and K. Hata: EPR Characterization of Catalyst-free SWNT and N@C60 -based Peapods , Phys. Status Solidi B 243 , 3273–3276 (2006). B. Corzilius, E. Ramić, and K.-P. Dinse: HYSCORE Analysis of Nitrogen Hyperfine Interactions , Appl. Magn. Res. 30 , 499–512 (2006).
B. Corzilius, A. Gembus, K.-P. Dinse, F. Simon, and H. Kuzmany: Carbon Nanotubes Investigated by N@C60 and N@C70 Spin Probes , in: Electronic Properties of Novel Nanostructures , eds. H. Kuzmany, J. Fink, M. Mehring, and S. Roth, AIP Conference Proceedings 786, pp. 291-295, Melville, New York, 2005 . B. Corzilius, A. Gembus, N. Weiden, and K.-P. Dinse: Preparation and EPR Characterization of N@C60 -based Peapods , in: Electronic Properties of Novel Nano-structures , eds. H. Kuzmany, J. Fink, M. Mehring, and S. Roth, AIP Conference Proceedings 786, pp. 317-320, Melville, New York, 2005 .
back to top